摘要
标题化合物的分子和晶体结构最初是用照相法进行测定的〔１〕。Ｆｌｅｉｓｃｈｅｒ等认为，在这个卟啉锌配合物中Ｚｎ离子处于卟啉大环平面正中央，并上下各络合距离为２．４５的水分子，从而形成（４Ｎ＋２Ｏ）的六配位八面体构型。随后，Ｈｏａｒｄ等从晶体计算密度和...
Abstract The structure of ZnTTP(H2O) is not monoclinic, as reported by Ruan, Zhu, Bu, Zhang, Shao and ChenChinese J. Structure Chemistry, 1998, 17(3):159￣164 but tetragonal. The revised crystal data are a=13.382(5), c=9.672(2) in space group I4/m, Z=2, which are consistent with that reported in the prvious literalures, especially the one published by Golder, Povey, Silver and Jassim Acta Crystallogr., 1990, C46: 1210￣1212.
