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高浓度超高相对分子质量聚乙烯冻胶流变行为的研究

Study on Rheological Behavior of High-concentration Ultra High Molecular Weight Polyethylene Gel
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摘要 应用Rosand RH7D型双料筒毛细管流变仪,研究了以白油为溶剂的高浓度超高相对分子质量聚乙烯(UHMWPE)冻胶的流变特性,以及冻胶浓度、温度对高浓度冻胶的流变曲线、非牛顿指数和结构黏度指数的影响。结果表明:高浓度UHMWPE冻胶属于宾汉流体,不同浓度的UHMWPE冻胶非牛顿指数随温度的升高先增大后减小,结构黏度指数随UHMWPE冻胶浓度及温度的增高而减小。 The rheological behavior of high concentration UHMWPE gel was studied by a Rosand RH7D double-barrel capillary rheometer.The effects of gel concentration and temperature on rheological curve,non-Newtonian index and structural viscosity index of the gel were analyzed.The results indicated that high concentration UHMWPE gel belonged to Bingham fluid and all non-Newtonian index of different concentration gel showed a trend of first increase and then decrease with increasing gel temperature.The structural viscosity index decreased with increasing of UHMWPE gel concentration and increasing of gel temperature.
出处 《合成纤维》 CAS 2010年第11期10-14,共5页 Synthetic Fiber in China
基金 上海市重点学科建设资助项目(项目编号B603)
关键词 超高相对分子质量聚乙烯纤维 冻胶纺 高浓度 流变行为 UHMWPE fiber gel spinning high concentration rheological behavior
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  • 1Capaccio, Crompton T A, Ward I M J. Properties of Ultra-high molecular weight polyethylene [ J ]. Polym Sci ( Polym Physics ) ,1976,14(9) :1 641-1 658.
  • 2Smith P, Lemstra P J, Booij H C J. Gel spinning of Ultra-high molecular weight polyethylene [ J ]. Polym Phys Ed, 1981, ( 19 ) :877-886.
  • 3刘维锦,沈家瑞.聚苯胺纺丝溶液的流变性质[J].华南理工大学学报(自然科学版),2000,28(3):96-100. 被引量:8

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