摘要
Ｃ６０与正丙胺反应，然后分别与氯亚铂酸钾或三氯化铑配合，制得了含配位氮原子的富勒烯铂、铑配合物．它们均能有效地催化烯烃与三乙氧基硅烷的硅氢加成，铂配合物还对苯乙烯有独特的催化性能，以近１００％的区域选择性得到α－加成产物．对催化机理进行了初步的探讨．
Fullerene n \|propylamine platinum and rhodium complexes were prepared by reaction of C60 with n \|propylamine, followed by complexing with potassium chloroplatinite or rhodium chloride respectively. These two complexes were effective catalysts for hydrosilylation of olefins with triethoxysilane. The Pt complex exhibited nearly 100% regioselectivety for styrene \|adduct. The mechanism of hydrosilylation was also discussed.
出处
《分子催化》
EI
CAS
CSCD
北大核心
1999年第2期87-92,共6页
Journal of Molecular Catalysis(China)
基金
国家自然科学基金
关键词
富勒烯
硅氢化
催化剂
C60
正丙胺
锗
铑
配合物
Fullerene Hydrosilylation catalyst Regioselectivity Mechanism Studies on Selective Oxidation of C-H Bond Catalyzed by Ruthenium ComplexesYIN Guochuan XI Zuwei CAO Guoying FAN Shuhua HAI Xiaodan (Dalian Institute of Chemical Physics The Chinese A
