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对二茂铁苯甲酸构筑的一维链状配位聚合物[Pb（η^2-FcL）2（phen）]n的合成、晶体结构和性质 被引量：1

Synthesis,Crystal Structure and Property of 1D Chain Coordination Polymer [Pb（η^2-FcL）2（Phen）]n Based on p-Ferrocenylbenzoate
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摘要 0引言 基于二茂铁及其衍生物独特的结构特征、灵活多样的配位模式,以及该类化合物在非线性光学材料、分子磁体材料、液晶材料以及均相催化等领域的重要用途而倍受关注。人们尝试通过把二茂铁引入到其他的分子体系中得到一些新型的含二茂铁基的化合物,其中二茂铁羧酸衍生物作为一类性能优良的配体已被广泛应用于构筑功能配合物,并且已有较多的二茂铁单甲酸、二茂铁双甲酸的配合物被报道。 A new 1D chain coordination polymer [Pb（η^2-FcL）2（phen）]n is obtained by slow evaporation of the solution, and characterized by the elemental analyses, 1↑H NMR, IR and thermogravimetric analysis. The crystal structure has been analyzed by X-ray diffraction. The title complex belongs to triclinic system with space group P1. Each Pb（Ⅱ） ion is coordinated by O atoms from carboxylic of p-ferrocenylbenzoate in μ3-bridge mode and the N atoms from phenanthroline in chelated mode. The Pb（Ⅱ） ions are connected by bridging O atoms leading to the infinite 1D chain. In addition, the π-π stacking interaction between the phenanthroline molecules can increase the stability of the complex. The thermogravimetry analysis indicates that the this complex is stable before 255.9 ℃.
作者 顾立强 李杰 傅亚丽 冉春玲 徐琰 樊耀亭
机构地区 郑州大学化学系
出处 《无机化学学报》 SCIE CAS CSCD 北大核心 2010年第11期2113-2116,共4页 Chinese Journal of Inorganic Chemistry
基金 国家自然科学基金资助项目(No.20871106)
关键词 二茂铁苯甲酸 邻菲咯啉 配位聚合物 晶体结构 热稳定性 ferrocenylbenzoate phenanthroline coordination polymer crystal structure thermal stability
分类号 O614.433 [理学—无机化学]
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  • 1Togni,A.;Hayashi,T.Ferrocenes,Homogenous Catalysis,Organic Synthesis,Materials Science,VCH,Weinheim,1995.
  • 2Miller,J.S.;Epstein,A.J.Angew.Chem.,Int.Ed.Engl.1994,33,385.
  • 3(a) Long,N.G.Angew.Chem.,Int.Ed.Engl.1995,34,21.(b) Nguyen,P.;C omez-Elipe,P.;Manners,I.Chem.Rev.1999,99,1515.(c) Hu,P.;Zhao,K.-Q.;Xu,H.-B.;Zhang,L.-F.Acta Chim.Sinica 2002,60,1682 (in Chinese).(胡平,赵可清,许洪波,张良辅
  • 4Slocum,D.W.;Ernst,C.R.Adv.Organomet.Chem.1972,10,106.
  • 5(a) Costa,R.;Lo′pez,C.;Molins,E.;Espinosa,E.;Pe′rez,J.J.Chem.Soc.,Dalton Trans.2001,2833.(b) Lo′pez,C.;Costa,R.;Illas,F.;Molins,E.;Espinosa,E.lnorg.Chem.2000,39,4560.(c)lee,S.-M.;Cheung,K.-K.;Wong,W.-T.J.Organomet.Chem.1996,506,77.(d)Prokopuk,N.;Shrive
  • 6(a) Li,Z.-J.;Liu,C.-R.;Lian,G.-W.Chin.Rare Earths1994,15(3),4 (in Chinese).(李中军,刘长让,廉革伟,稀土,1994,15(3),4.)(b) Hao,M.-R.;Li,M.Chin.Rare Earths 1994,15(6),4( in Chinese).(郝茂荣,李梅,稀土,1994,15(6),4)(c) Li,M.;S
  • 7(a) Schmitt,G.;Ozman,S.J.Org.Chem.1976,41,3331.(b) Gmelin Handbuch der Anorganische Chemie,Eisen Organische Verbindungen,Vol.A3,Springer-Verlag,Berlin,1976,p.58.
  • 8Sheldrick,G.M.SHELX-97,Program for the Solution and Refinement of Crystal Structures,University of Gottingen,Germany,1997.
  • 9(a) Bergamini,P.;Martino,S.D.;Maldotti,A.;Sostero,S.J.Organomet.Chem.1989,365,341.(b) Li,G.;Hou,H.-W.;Li,L.-K.;Meng,X.-R.;Fan,Y.-T.;Zhu,Y.Inorg.Chem.2003,42,4995.
  • 10Allen,T.H.;Kennard,O.Chem.Des.Automat.News 1993,8,146.

共引文献15

同被引文献13

  • 1徐琰,张茂林,王海先,宋毛平,吴养洁.二茂铁基苯甲酸铜(Ⅱ)双核簇合物的合成、晶体结构及电化学性质[J].化学研究,2005,16(3):1-5. 被引量：1
  • 2MengXR, LiG, HouHW, etal. A sefiesofnovelmetal - ferrocenedicarboxylate coordination polymers : crystal structures, magnetic and luminescence properties [ J ]. J Organomet Chem,2003,679 : 153 - 161.
  • 3Li L K,Li X H,Hou H W,et al. Syntheses and structures' influence on the nonlinear optical properties of o - ferro- cenylbenzoate compounds [ J ]. Inorg Chim Acta, 2009, 362:599 - 604.
  • 4Li J P,Song Y L,Hou H W,et al. 1 -D polymeric diva- lent metal m- ferrocenylbenzoates: structures, NLO and electrochemical properties [ J ]. J Org Chem, 2007,692 : 1584 - 1592.
  • 5Liu B Q, Yan P F,Zhang J W, et al. Syntheses and struc- tures of four copper( Ⅱ ) complexes constructed from m - ferrocenylbenzoate and N - donor ligands [ J ]. J Org Chem,2012, 710:80 - 85.
  • 6Liu B Q, Yah P F, Zhang J W, et al. m - ferrocenylbenzo- ate - bridged lanthanide coordination polymers : syntheses, structures, electrochemical and magnetic properties [ J ]. J Org Chem,2010,695:2441 -2446.
  • 7Hou H W, Li L K, Zhu Y, et al. Novel one - dimensional polymers generated from p - ferrocenylbenzoate : synthe- ses, structures, and magnetic properties [ J ]. Inorg Chem, 2004,43 : 4767 - 4774.
  • 8Wang X, Li L K, Hou H W, et al. Substitution, addition,and recombination reactions of precursor complexes with ferrocenyl carboxylate units [ J ]. Eur J Inorg Chem, 2007, 33 : 5234 - 5245.
  • 9Yan P F, Zhang F M, Li G M, et al. Synthesis, crystal structures, magnetic and luminescent properties of u- nique 1D p - ferrocenylbenzoate - bridged lanthanide complexes[ J]. J Sol State Chem, 2009, 182:1685 - 1690.
  • 10张坤.二茂铁间苯甲酸基钴(Ⅱ)配合物的制备及晶体结构[J].河南科技学院学报,2009,37(2):49-51. 被引量：1

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无机化学学报
2010年 第11期

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