摘要
通过对非晶高聚物动态力学方法和前人的静态法(如膨胀计法或量热法)实验结果的比较,指出:用静态法测得的玻璃化转变温度Tg和用动态力学法测得的α内耗峰的峰温Tα虽然在温度上很接近,但物理本质不同,并对引起这种不同的微观物理机制作了一定的探讨.
Comparision between the results by dynamic mechanical and static methods has been made. The resoults show clearly that the T g determined by calorimetry or dilatometry and the peak temperature T α obtained by dynamic mechanical method have different physical origins, although T α is usually in the vicinity of T g. It is suggested that during dynamic mechanical measurement, two different processes (thermal relaxation and mechanical relaxation) be involved in simultaneously.
出处
《郑州工业大学学报》
CAS
1999年第1期24-25,共2页
Journal of Zhengzhou University of Technology
基金
国家自然科学基金