期刊文献+

非晶高聚物玻璃化转变过程的动态力学特征

Dynamic Mechanical Characters of the Glass Transition Progress in Amorphous Polymer
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摘要 通过对非晶高聚物动态力学方法和前人的静态法(如膨胀计法或量热法)实验结果的比较,指出:用静态法测得的玻璃化转变温度Tg和用动态力学法测得的α内耗峰的峰温Tα虽然在温度上很接近,但物理本质不同,并对引起这种不同的微观物理机制作了一定的探讨. Comparision between the results by dynamic mechanical and static methods has been made. The resoults show clearly that the T g determined by calorimetry or dilatometry and the peak temperature T α obtained by dynamic mechanical method have different physical origins, although T α is usually in the vicinity of T g. It is suggested that during dynamic mechanical measurement, two different processes (thermal relaxation and mechanical relaxation) be involved in simultaneously.
出处 《郑州工业大学学报》 CAS 1999年第1期24-25,共2页 Journal of Zhengzhou University of Technology
基金 国家自然科学基金
关键词 非晶高聚物 玻璃化转变 高聚物 动态力学法 amorphous polymer glass transition α internal friction peak
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参考文献1

  • 1何曼君,高分子物理(修订版),1990年,224,258页

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