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Al_(65)Cu_(20)Fe_(15)合金的凝固组织及二十面体准晶的生成 被引量:7

SOLIDIFICATION MICROSTRUCTURE OF A1_(65)Cu_(20)Fe_(15) ALLOY AND FORMATION OF ICOSAHEDRAL QUASICRYSTAL
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摘要 用X射线能谱分析、电子背散射衍射和粉末X射线衍射等技术研究了A165Cu20Fe15合金的铸往及其退火后的显微组织和相组成二发现铸锭中的初生晶是(AI,Cu)13Fe4;呈明显的枝晶结构枝晶间为十二面体准晶的菱面体近似相(R相)、CsCl结构的β相和微量的相和相.在随后800℃退火的过程,和相反应生成二十面体准晶,同时R相转变成二十面体准晶.退火后空冷,试样由十二面体准晶、少量相和微量的相组成. Microstructures and constituent phases of A165CuZoFe15 alloy, in both as cast state and postcast annealed state, were studied by means of energy dispersive X-ray spectrometry, electron backscat-ter diffraction and powder X-ray diffraction. This study revealed that the primary solidified phase is(Al,Cu)13Fe4 forming severe dendritic structure. Between dendritic arms there are rhombohedral Rphase, an approximant of icosahedral quasicrystal(IQC), β phase of CsCI structure and trace W and Ephases. During subsequent annealing at 800℃, A, P, W and E phases react forming IQC, and R phasetransforms into IQC. The air-cooled sample consists of IQC, small amount of A--(Al,Cu)13Fe4 phase andtrace β-Al(Fe,Cu) phase.
出处 《金属学报》 SCIE EI CAS CSCD 北大核心 1999年第5期463-468,共6页 Acta Metallurgica Sinica
基金 国家自然科学基金!59771049
关键词 凝固组织 准晶 二十面体 铝合金 solidification microstructure, Al-Cu-Fe alloy, quasicrystal
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参考文献3

  • 1Dong C,J Phys Condens Matter,1990年,2卷,6339页
  • 2Dong C,J Mater Sci Lett,1989年,8卷,827页
  • 3Tsai A P,J Mater Sci Lett,1987年,6卷,1403页

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