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Synthesis of Polyaniline-Fe_3O_4 Nanocomposites and Their Conductivity and Magnetic Properties

Synthesis of Polyaniline–Fe_3O_4 Nanocomposites and Their Conductivity and Magnetic Properties
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摘要 By using inorganic Fe3O4 nanoparticles of different content as nucleation sites, PAn-Fe3O4 nanorods were successfully synthesized through a simple, conventional, and inexpensive one-step in-situ polymerization method. The TEM images revealed the size and morphology of the resultant nanocomposite. The EDS pattern confirmed the existence of Fe3O4 in the composite. The FT-IR spectral analysis confirmed the formation of PAn encapsulated Fe3O4 nanocomposite. With the content of Fe3O4 increasing, the conductivity of the nanocomposites gradually decreases, meanwhile, the saturation magnetization increases and reveals a super paramagnetic behavior. With controllable electrical, magnetic, and electromagnetic properties, the well-prepared nanocomposites may have the potential applications in chemical sensors, catalysis, microwave absorbing, and electro-magneto-rheological fluids, etc. By using inorganic Fe3O4 nanoparticles of different content as nucleation sites, PAn-Fe3O4 nanorods were successfully synthesized through a simple, conventional, and inexpensive one-step in-situ polymerization method. The TEM images revealed the size and morphology of the resultant nanocomposite. The EDS pattern confirmed the existence of Fe3O4 in the composite. The FT-IR spectral analysis confirmed the formation of PAn encapsulated Fe3O4 nanocomposite. With the content of Fe3O4 increasing, the conductivity of the nanocomposites gradually decreases, meanwhile, the saturation magnetization increases and reveals a super paramagnetic behavior. With controllable electrical, magnetic, and electromagnetic properties, the well-prepared nanocomposites may have the potential applications in chemical sensors, catalysis, microwave absorbing, and electro-magneto-rheological fluids, etc.
作者 冷春江
出处 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2010年第5期760-764,共5页 武汉理工大学学报(材料科学英文版)
基金 Funded by National Natural Science Foundation of China(No.10974148) Sub-project of State Key Development Program of Basic Research of China(Nos. 2009CB939704 and 2009CB939705)
关键词 POLYANILINE FE3O4 NANOCOMPOSITES CONDUCTIVITY super paramagnetism polyaniline Fe3O4 nanocomposites conductivity super paramagnetism
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