期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

松香基尾巴新型双子表面活性剂的焓熵补偿 被引量：2

Enthalpy-entropy Compensation of the Gemini Surfactant CsH_2 s-α,ω-bis(dehydroabietyl-hydroxypropylteteramethylethylammonium Chloride)
在线阅读 下载PDF
导出
摘要 为研究双子(Gemini)表面活性剂结构中疏水"尾巴"对其在水溶液中行为的影响,对以脱氢松香酰基为疏水链"尾巴"的季铵盐双子表面活性剂二氯化-N,N′-二(3-脱氢松香酰氧-2-羟丙基)四甲基乙二胺的胶团化行为进行了研究,发现焓变(ΔH)和熵变(ΔS)呈线性关系,表明其胶团化过程存在焓熵补偿现象,补偿温度为310.8 K左右,为熵驱动过程。 To study the relationship between the ＂tail＂ structure and the behavior of Gemini surfactants in aqueous solution,the thermodynamic parameters of micellization of a new Gemini surfactant CsH2s-α,ω-bis（dehydroabietylhydroxypropylteteramethylethylammonium chloride）,with dehydrogenated rosin as hydrophobic ＂tails＂ in the structure were investigated.When enthalpy of interaction（ΔH） was plotted against entropy（ΔS）,linear plots were obtained.This indicates the clear enthalpy-entropy compensation with a compensation temperature of approximately 310.8 K.
作者 李海朝 胡旭
机构地区 东北林业大学材料科学与工程学院
出处 《林产化学与工业》 EI CAS CSCD 北大核心 2010年第5期65-68,共4页 Chemistry and Industry of Forest Products
基金 黑龙江省自然科学基金资助项目(42400625-4-08163) 国家自然科学基金资助项目(30760195)
关键词 双子表面活性剂 焓熵补偿 松香 Gemini surfactant enthalpy-entropy compensation rosin
分类号 TQ35 [化学工程] TQ423.4 [化学工程]
  • 相关文献

参考文献10

  • 1MENGER F M, KEIPER J S. Gemini surfactants[ J]. Angew Chem Int Ed ,2000,39( 11 ) : 1906-1920.
  • 2ZANA R. Effect of the spacer group on the association behavior in aqueous solution [ J ]. Journal of Colloid and Interface Science,2002,248 (2) :203-220.
  • 3姚志钢,李干佐,董凤兰,胡艾希.Gemini表面活性剂合成进展[J].化学进展,2004,16(3):349-364. 被引量：61
  • 4LI Z X, DONG C C, THOMAS R K. Neutron reflectivity studies of the surface excess of Gemini surfactants at the air-water interface [ J ]. Langmuir, 1999,15 ( 13 ) :4392-4396.
  • 5TORRES J L, PIERA E, INFANTE M R, et al. Purification of non-toxic, biodegradable arginine-based gemini surfactants by ion exchange chromatography [ J ]. Preparative Biochemistry and Biotechnology ,2001,31 ( 3 ) :259-274.
  • 6乐治平,李丽,李凤仪.松香扩链双马来酰亚胺的合成与表征[J].应用化学,1999,16(3):49-52. 被引量：8
  • 7胡旭,李海朝,陈立云.二氯化-N,N-′-二(3-脱氢松香酰氧-2-羟丙基)四甲基乙二胺的合成与性能[J].应用化学,2007,24(12):1439-1442. 被引量：7
  • 8GAILLON L, LELIEVRE J, GABORIAUD R. Counterion effects in aqueous solutions of cationic surfaetants: Electromotive force measurements and thermodynamic model [ J ]. Journal of Colloid and Interface Science, 1999,213 (2) :287-297.
  • 9JALSENJAK N,TEZAK D. A new method for simultaneous estimation of micellization parameters from conductometrie data[ J]. Chemistry--A European Journal,2004,10 ( 20 ) : 5000-5007.
  • 10刘金彦,李海朝,孙世鹏.Gemini表面活性剂气液界面吸附过程的焓熵补偿[J].武汉理工大学学报,2007,29(11):47-50. 被引量：3

二级参考文献39

  • 1郝建军,江璐霞,蔡兴贤.含硅双马来酰亚胺的合成及表征[J].高分子材料科学与工程,1994,10(2):110-115. 被引量：8
  • 2程芝.－[J].化工时刊,1997,11(5):57-57.
  • 3Chen L J, Lin S Y, Huang C C. Effect of Hydrophobic Chain Length of Surfactants on Enthalpy-entropy Compensation of Micellization[J]. J Phys Chem B, 1998,102(22) : 4350-4356.
  • 4Tanford C. The Hydrophobic Effect: Formation of Micelles and Biological Membranes[M]. New York: Wiley Press, 1980.
  • 5Rosen M J. Geminis: a New Generation of Surfactant[J]. Chemtech, 1993,23(3) :30-33.
  • 6Menger F M, Littau C A. Gemini Surfactants: Synthesis and Properties[J]. J Am Chem Soc,1991,113(4) :1451-1452.
  • 7Zana R, Benrraou M, Rueff R. Alkanedily-α, ω-bis (Dimethylalkylammonium Bromide) Surfactants (Dimeric Surfactants). I. Effect of the Spacer Chain Length on the Critical MiceUe Concentration and Micelle Ionization Degree[J ]. Langmuir, 1991, 7(6) : 1072-1075.
  • 8Zana R. Dimeric (Gemini) Surfactants: Effect of the Spacer Group on the Association Behavior in Aqueous Solution[J]. J Colloid and Interface Sci, 2002,248(2) :203-220.
  • 9Alami E, Beinert G, Marie P, et al. Alkanediyl-α, ω-bis(Dimethylammonium Bromide)Surfactants. 3. Behavior at the Air- Water Interface[J]. Langrnuir, 1993,9 (6) : 1465-1467.
  • 10Rosen M J, Aronson S. Standard Free Energies of Adsorption of Surfactants at the Aqueous Solution/air Interface from Surface Tension Data in the Vicinity of the Critical Micelle Concentration[J]. Colloids Surf, 1981,3(3) :201-208.

共引文献75

同被引文献27

  • 1张光华,解攀,刘静,李慧.松香型阳离子乳化剂的制备及性能[J].化工进展,2008,27(10):1628-1631. 被引量：6
  • 2ZANA R.Dimeric and oligomeric surfactants.Behavior at interfaces and in aqueous solution.A review[J].Advances in Colloid and Interface Science,2002,97(1/2/3):205-253.
  • 3CAPPELAERE E,CRESSELY R,DECRUPPE J P.Linear and non-linear rheological behaviour of salt-free aqueous CTAB solutions[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,1995,104(2/3):353-374.
  • 4AIT ALI A,MAKHLOUFI R.Effect of organic salts on micellar growth and structure studied by rheology[J].Colloid and Polymer Science,1999,277(2/3):270-275.
  • 5CANDAU S J,HIRSCH E,ZANA R,et al.Rheological properties of semidilute and concentrated aqueous solutions of cetyltrimethylammonium bromide in the presence of potassium bromide[J].Langmuir,1989,5(5):1225-1229.
  • 6KERN F,LEQUEUX F,ZANA R,et al.Dynamic properties of salt-free viscoelastic micellar solutions[J].Langmuir,1994,10(6):1714-1723.
  • 7ZANA R.Alkanediyl-α,ω-bis(dimethylalkylammonium bromide) surfactants:II.Krafft temperature and melting temperature[J].Journal of Colloid and Interface Science,2002,252(1):259-261.
  • 8LI H Z,YANG H Y,YAN Y F,et al.Synthesis and solution properties of cationic Gemini surfactants with long unsaturated tails[J].Surface Science,2010,604(13/14):1173-1178.
  • 9CATES M E,TURNER M S.Flow-induced gelation of rodlike micelles[J].Europhysics Letters,1990,11(7):681-69-86.
  • 10CANDAU S J,ODA R.Linear viscoelasticity of salt-free wormlike micellar solutions[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2001,183-185(SI):5-14.

引证文献2

二级引证文献7

林产化学与工业
2010年 第5期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部