摘要
在常规条件下合成了标题化合物,并通过X-射线单晶结构分析、元素分析、红外光谱对晶体进行表征。结果表明,化合物属于单斜晶系,空间群P2(1)/n。对化合物进行了量子化学计算,用于说明其结构特征。
Three one-dimensional（1D） chain-like heteropolyoxotungstates Na10{[（M（H2O）3）2（WO2）2-（BiW9O33）2]}·xH2O（M=MnⅡ,CoⅡ,NiⅡ） were obtained in aqueous solution and were characterized by IR,elemental analysis and single-crystal X-ray analysis.Analytical data identified that the crystals of said complexes belonged to a monoclinic system with a space group of P2（1）/n.Finally,quantum chemistry calculations of complexes were performed to explain the structure characteristics.
出处
《化学试剂》
CAS
CSCD
北大核心
2010年第10期917-920,927,共5页
Chemical Reagents
基金
广西省自然科学基金资助项目(0832280)
关键词
多金属氧酸盐
铋
晶体结构
量子化学
polyoxometalate
bismuth
crystal structure
quantum chemistry
