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重整过程的热力学分析 被引量:1

THERMODYNAMIC ANALYSIS OF THE REFORMING PROCESS
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摘要 本文利用平衡常数法对重整过程中环己烷类、环戊烷类和烷烃的芳构化反应及烃的异构化和裂解反应进行热力学计算,并着重分析环戊烷类的异构脱氢和开环反应之间以及正构烷烃和各类烃之间的平衡关系。同时,结合重整过程讨论热力学分析的用处和它的局限性。文中还叙述了本文的计算方法。 Thermodynamic calculation of the aromatization, isomerization and hydrogenolysis reactions of alkylcyclohexanes, alkylcyclopentanes and paraffins during the catalytical reforming process were carried out by means of equilibrium constant method. The equilibrium relationship between isomerization-dehydrogenation and ring-opening reaction of alkylcyclopentanes as well as that between normal paraffins and other type hydrocarbons was emphatically analyzed. The application and limitation of thermodynamic analysis for reforming process were discussed. The method of calculation was also described.
作者 翁长武
机构地区 华侨大学
出处 《石油学报(石油加工)》 EI CAS CSCD 北大核心 1990年第1期84-91,共8页 Acta Petrolei Sinica(Petroleum Processing Section)
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