摘要
本文主要研究了N2O3与甲醇反应生成亚硝酸甲酯的反应动力学。发现N2O3与液相甲醇之间不发生反应,N2O3只与气相的甲醇发生反应生成亚硝酸甲酯。此外,本文通过动力学研究获得了N2O3与气相甲醇反应生成亚硝酸甲酯的反应动力学方程。通过计算值和实验值比较,表明得到的动力学方程有较高的可靠度。
Kinetics of the reaction of N2O3 with methanol to form methyl nitrite （MN） was investigated in a double-stirring reac- tor. It was found that the reaetion only occurred in gas phase. Moreover, based on the experimental data, a power law rate model was used to represent the formation of MN. The comparison between the calculated and experimental values of MN formation rate indi- cated that the resulting kinetie equation was of highly reliable.
出处
《天然气化工—C1化学与化工》
CAS
CSCD
北大核心
2010年第4期12-15,21,共5页
Natural Gas Chemical Industry
