摘要
多吡啶钌配合物在光物理、光化学和核酸结构探测等方面都扮演着重要的角色。该文对钌（Ⅱ）与配体（Ｌ）咪唑并［４，５－ｆ］邻菲咯啉，２－（４－取代基）苯基咪唑并［４，５－ｆ］邻菲咯啉形成的同配配合物ＲｕＬ３２＋和混配配合物Ｒｕ（ｂｐｙ）２Ｌ２＋、Ｒｕ（ｐｈｅｎ）２Ｌ２＋（ｂｐｙ和ｐｈｅｎ分别为２，２′－联吡啶和邻菲咯啉）的电子吸收光谱，发光光谱，红外光谱进行了综合研究，测定了发光配合物的发光寿命。
The electronic absorption, luminescent and infrared spectra of ruthenium complexes with homogenetic or heterogenetic ligands of imidazophenanthrolines, namely, RuL32+, Ru(bpy)2 L2+ and Ru(phen)2 L2+( L denotes one of the series of imidazophenanthroline ligands, bpy and phen are 2,2′ _ bipyridine and 1,10 _ phenanthroline, respectively) were studied comprehensively. The excited state lifetimes of the luminescent complexes were measured.
出处
《分析测试学报》
CAS
CSCD
1999年第2期17-20,共4页
Journal of Instrumental Analysis
基金
广东省自然科学基金
广东省高教厅1998年度自然科学重点科研项目资助
关键词
钌
配合物
光谱
咪唑并邻菲咯啉
Ruthenium, Imidazophenanthroline, Coordination compound, Electronic absorption spectrum, Luminescent spectrum, Infrared spectrum
