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一氧化碳中选择氧化除氢催化剂的研究 被引量:3

SELECTIVE OXIDATION OF HYDROGEN CONTAINED IN CARBON MONOXIDE
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摘要 Several supported Pd catalysts were prepared and their catalytic activity for selective oxidation of hydrogen was studied. The results show that the variety of the supports has great effect on the catalytic activity. The space velocity and the Pd loading show also certain influence. The most active catalyst Pd/C A can selectively remove H 2 at 170~200℃ and 1?800 h -1 from a feed gas consisting of H 2 (0 197%), O 2 (0 103%), CO (40%) and N 2 (balance). When CO content in the feed gas increases to 78%, the activity of the catalyst only decreases a little, indicating that the results obtained here seems applicable to the removal of H 2 from pure CO. Several supported Pd catalysts were prepared and their catalytic activity for selective oxidation of hydrogen was studied. The results show that the variety of the supports has great effect on the catalytic activity. The space velocity and the Pd loading show also certain influence. The most active catalyst Pd/C A can selectively remove H 2 at 170~200℃ and 1?800 h -1 from a feed gas consisting of H 2 (0 197%), O 2 (0 103%), CO (40%) and N 2 (balance). When CO content in the feed gas increases to 78%, the activity of the catalyst only decreases a little, indicating that the results obtained here seems applicable to the removal of H 2 from pure CO.
出处 《催化学报》 SCIE CAS CSCD 北大核心 1999年第2期185-187,共3页
关键词 一氧化碳 纯化 选择氧化 除氢 催化剂 carbon monoxide, purification, hydrogen, selective oxidation, palladium
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参考文献2

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同被引文献19

  • 1戚建英,杨启云,李贤均.一氧化碳氧化的钯-铈催化剂性能研究[J].化学研究与应用,1996,8(3):391-396. 被引量:2
  • 2陈五平.无机化工工艺学 (一)合成氨[M].北京:化学工业出版社,1991..
  • 3张成芳.合成氨工艺与节能[M].上海:华东化工学院出版社,1989..
  • 4陈五平.无机化工工艺学,(一)合成氨[M].北京:化学工业出版社,1991..
  • 5陈贻盾.气相催化合成草酸酯连续工艺[P].中国:CN 1054765A.1991.
  • 6劲秋.煤制乙二醇路线及其应用[J].精细化工原料及中问体,2011,(12):25-32.
  • 7孔渝华,胡典明,钱胜涛,等.一氧化碳原料气脱氢催化剂及其制备和应用方法:中国,CN101543776[P].2009-09-30.
  • 8姚元根,周张锋,乔路阳,等.一种双金属合成气脱氢净化催化剂及其制备方法:中国,CNl02302938A[P].2011-06-30.
  • 9崔波,张青瑞,曹长青,刘新鹏,张洪全,陈开泰.B_(117)催化剂上一氧化碳中温变换的本征动力学[J].高校化学工程学报,1997,11(1):55-61. 被引量:8
  • 10陈贻盾,李国方.“用煤代替石油乙烯合成乙二醇”的技术进步[J].中国科学技术大学学报,2009,39(1):1-10. 被引量:29

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