摘要
首次采用ＧＣ及ＧＣ／ＭＳ方法分别对苄基氯、对硝基苄基溴与多硫化钠反应进行了分析，并确定了反应的中间体结构：节基二硫化物及氨基苄基硫化物。通过对反应过程研究与讨论，为ＰＮＴ与多硫化钠反应机理研究提供了证据。
The reaction of benzyl chloride, p-nitrobenzylbromide with sodium polysulfide were first analysized by GC and GC/MS, respectively, and structures of the intermediates were determined:benzyl disulfide and aminobenzylsufide. Through reseaches and discussions of the re-action procedures,many evidences were given for the mechanism of PNT with sodium polysulfide.
出处
《黑龙江大学自然科学学报》
CAS
1999年第1期94-97,共4页
Journal of Natural Science of Heilongjiang University
基金
黑龙江省教委基金
关键词
芳香族
硝基化
多硫化钠
苄基卤化物
GC/MS
words Benzyl chloride
P-nitrobenzyl bromide
Benzyl disulfide
Aminobenzyl sulfide
GC/MS
