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壳聚糖-多壁碳纳米管/二茂铁修饰玻碳电极的电催化研究 被引量:2

Electrocatalysis study of multi-wall carbon nanotubes and ferrocene/chitosan composite film modified glass carbon electrode
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摘要 利用多壁碳纳米管(MWCNTs)分散在壳聚糖/二茂铁形成的混合溶液,采用滴涂法对玻碳电极进行修饰,对多巴胺(DA)进行测定。结果表明,修饰后的玻碳电极能够有效促进DA在电极表面的电子传递速率,并且修饰电极对DA具有很好的催化氧化作用。DA氧化峰电流与其浓度在0.5~25μmol/L范围内呈良好的线性关系,检出限为3.89×10-7mol/L,并且常见物质对DA检测无干扰,DA注射液样品检测回收率为98.1%~100.9%。 A robust and effective composite film combined the benefits of ferrocene(Fc),chitosan(CHIT) and multi-wall carbon nanotubes(MWCNTs) was prepared.The composite film performed excellent electrocatalysis and acted as an electron transfer mediator.Under optimal conditions,this modified electrode was able to detect dopamine(DA) in the linear range of 0.5-25μmol /L with a detection limit of 3.89×10-7mol /L.And common impurities have no effect on the determination of DA.The modified electrode was applied to assessing the contents of DA and obtained a recovery of 98.1%-100.9%.
出处 《功能材料》 EI CAS CSCD 北大核心 2010年第A01期57-59,63,共4页 Journal of Functional Materials
基金 东华理工大学核资源与环境教育部重点实验室资助项目(081214)
关键词 壳聚糖 多壁碳纳米管 二茂铁 电催化作用 chitosan multi-wall carbon nanotubes ferrocene electrocatalysis
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