摘要
聚四氟乙烯(以下简称为F4)一直被认为是典型的辐射降解型高聚物,但事实上F4在特定条件(无氧及一个很窄的温度区间(335±5℃))下是可以实现辐射交联的。辐射交联F4与辐射裂解F4相比,其性质(如结晶度等)发生了很大的变化,与之相关的文献近几年已陆续发表,对此本文将给予扼要的回顾及总结。
Polytetrafluoroethylene (PTFE) has always been regarded as a typical kind of radiation degradation polymer. But, in fact, PTFE can be induced crosslinking by γ-ray or electron beam at some special conditions (free oxygen and a narrow temperature region at 335±5℃).Compared with radiation degradation PTFE, cosslinking PTFE owns a lot of new properties. Some articles concerning with these have been published, which will be systematically reviewed in this.
出处
《辐射研究与辐射工艺学报》
CAS
CSCD
北大核心
1999年第1期1-8,共8页
Journal of Radiation Research and Radiation Processing
关键词
辐射裂解
辐射交联
聚四氟乙烯
Radiation degradation, Radiation crosslinking, Polytetrafluoroethylene