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五价钽、锂掺杂对Y-TZP微观结构和性能的影响 被引量:3

The Influence of Pentavalent Transition Metal Oxide on theMicrostructure and Properties of Y-TZP
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摘要 在前人工作的基础上,本文作者进一步深入细致地分析总结了Nb2O5和Ta2O5对Y-TZP微观结构和宏观性能的影响并提出自已的见解。研究发现Nb2O5和Ta2O5的添加使得Y-TZP轴比及热膨胀各向异性增大,马氏体相变起始温度升高,可相变t-ZrO2含量上升有利于材料机械性能的提高。 On the basis of several other scientists' work,the s made a further intensive and careful investigation about the influence of Nb2O5 and Ta2O5 on the microstructure and macroproperties of Y-TZP,and thus put forwards some unique opinions of his own.It was found that the addition of Nb2O5 and Ta2O5 increased the tetragonality and the thermal anisotropy of Y-TZP crystal.Further more,the starting temperature of the t-ZrO2m-ZrO2 martensitic transformation was raised.Due to the increase of this temperature,the thermodynamic driving force for this transfomation was enhanced and the transformable t-ZrO2 fraction under the influence of crack-tip stress field was increased,which was helpful for the improvement of the fracture toughness.And because of the solid solution of Ta5+ and Nb5+,which were small in cation radius and big in electric charge,in zirconia crystal lattice,Zr-O band strength was increased and so did the fracture strength of the ceramics as a whole.
机构地区 天津大学材料系
出处 《硅酸盐通报》 CAS CSCD 1999年第2期52-54,61,共4页 Bulletin of the Chinese Ceramic Society
关键词 Y-TZP 五氧化钽 五氧化锂 氧化锆陶瓷 结构 性能 Nb2O5,Ta2O5,Y2O3,Y-TZP,additive,martensitic transformation
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  • 2申云军,黄校先.氧化钇含量对Al_2O_3/Y-TZP复相陶瓷的影响[J].无机材料学报,1996,11(2):259-263. 被引量:8
  • 3路新瀛,梁开明,顾守仁,方鸿生,郑燕康,刘鹏.氧化锆在电场下的相变[J].硅酸盐学报,1996,24(3):329-332. 被引量:4
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