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二茂铁衍生物对Ru(bpy)3^2＋发光猝灭的研究

Study on the queching of ferrocene derivatives to Ru(bpy)_3^(2+)
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摘要 研究二茂铁衍生物对Ru(bpy)32+的发光猝灭.按照文献[8-9]合成7种二茂铁衍生物,发现它们对Ru(bpy)32+的发光有明显的猝灭作用,通过Stern-Volmer公式分别求出了它们的猝灭速率常数kg和自由能变△G.研究了它们猝灭Ru(bpy)32+发光过程中的电子转移机理. This paper was focused on the suppression of ferrocene derivatives to Ru（bpy）3^2＋.Seven ferrocene derivatives were synthesized according to the literature method,which were found to have an apparent quenching effect on the luminescence from Ru（bpy）3^2＋.Their quenching rate constants（kg） and the free energy change（△G） were also obtained from the Stern-Volmer equation.The electron transition mechanism was also investigated in the processes of luminescence from the suppression for the seven ferrocene derivatives to Ru（bpy）3^2＋.
作者 肖陆飞 左从玉 汪徐春 金葆康 吴杰颖 田玉鹏
机构地区 安徽大学化学化工学院 滁州职业技术学院基础部
出处 《安徽大学学报（自然科学版）》 CAS 北大核心 2010年第3期71-74,96,共5页 Journal of Anhui University(Natural Science Edition)
基金 国家自然科学基金资助项目(20771001) 安徽省高校自然科学基金资助项目(KJ2010B427)
关键词 二茂铁 衍生物 猝灭 速率常数 电子转移 ferrocene derivatives quenching rate constants electron transfer
分类号 O621.2 [理学—有机化学]
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参考文献15

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共引文献7

安徽大学学报（自然科学版）
2010年 第3期

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