摘要
利用INDO法及能量梯度方案,对H_3Si^+与1,3—双亲负离子形成的配合物进行了计算,讨论了配合物的构型、配位反应标度、结构之稳定性及成键特征,给出了配位反应的规律性,得出了一些结论。
The coordinstions formed from H_3Si^+ and 1,3-Ambident Anion have been calcnlated by INDO Method and energy gradient method. By analysing eoiulibl-ium geometries, reaction scale of coordination, stability of structure and binding characteristic, The law of coordinating reaction and beneficial conclusions are given.
出处
《曲阜师范大学学报(自然科学版)》
CAS
1990年第3期66-69,共4页
Journal of Qufu Normal University(Natural Science)
关键词
硅化物
络合物
双亲负离子
配位能
stabilization energy, coordination energy, band daramter.