期刊文献+

用带滑动函数的Rouse-Zimm模型说明某些中等稀聚合物溶液的非线性粘弹性

PREDICTION OF THE NON-LINEAR RHEOLOGY OF SOME POLYMER SOLUTIONS BY MEANS OF THE ROUSE-ZIMM MODEL WITH SLIPPAGE
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摘要 本文介绍了非仿射变形假定和滑动函数的基本概念,利用Cox-metz关系式为一类中等稀聚合物溶液确定滑动函数的形式,带滑动函数的Rouse-Zimm模型被用来定量说明此类材料的非线性流变性,一些公开发表的实验数据被引证。理论结果与实验数据吻合良好。 Non-affine deformation and the slippage function are discussed. The slippage function is determined for some polymer solutions with moderate concentration by means of the Cox-Merz rule. The non-linear viscoelasticity of these solutions is described with the aid of the Rouse-Zimm model with slippage function. The theoretical predictions show good agreement with published experimental data.
作者 吴其晔
机构地区 青岛化工学院
出处 《高分子学报》 SCIE CAS CSCD 北大核心 1989年第2期200-207,共8页 Acta Polymerica Sinica
关键词 聚合物溶液 非线性粘弹性 Slippage, Rouse-Zimm model, Polymer solution, Cox-Merz rule, Nonlinear viscoelesticity
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参考文献3

  • 1Y. T. Hsü,P. Schümmer. Quantitative description of rheological properties of dilute polymer solutions[J] 1983,Rheologica Acta(4):348~353
  • 2K. Yasuda,R. C. Armstrong,R. E. Cohen. Shear flow properties of concentrated solutions of linear and star branched polystyrenes[J] 1981,Rheologica Acta(2):163~178
  • 3W. W. Graessley,W. S. Park,R. L. Crawley. Experimental tests of constitutive relations for polymers undergoing uniaxial shear flows[J] 1977,Rheologica Acta(3):291~301

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