摘要
本文简述了乳浓聚合动力学研究的进展,着重于澳大利亚Sydney大学Gilbert等在乳液聚合阶段Ⅱ动力学方面的研究概况。介绍了不同水溶性单体的小尺寸种子乳液体系的SmithEwart递推方程的求解方法及其解析解形式和乳液聚合动力学数据的处理。同时讨论了该研究的局限性。
This paper reviewed the advances in the kinetic study on emulsion polymerization, mainly the reseach works on Interval Ⅱ done by Gilbert. It also introduced in this paper the kinetic treatments and solutions of the Smith-Ewart generalized equation for the small particle size latex systems with monomers of various water solubilities. The limitations of the treatment were discussed.
出处
《高分子通报》
CAS
CSCD
1989年第2期24-31,共8页
Polymer Bulletin
关键词
乳液聚合
动力学
Emulsion polymerization, Small particle size seeded latex, Kinetic study, Smith-Ewart generalized equation