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氮-二供电子链取代邻苯二甲酰亚胺衍生物的光诱导单电子转移环化反应 被引量：6

Photoinduced Cyclization Reactions of Phthalimide Derivatives N-Linked Two Electrondonating Chains by Single Electron Transfer
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摘要 含有较短硫醚链和较长聚乙氧基醚链的邻苯二甲酰亚胺衍生物在甲醇溶剂中发生光诱导单电子转移环化反应(SET),以很高的反应区域选择性和很高的产率得到由较短的硫醚链参与构成的环状化合物.所有新化合物均经NMR和EI-MS确定其结构. Phthalimide derivatives containing a shorter thioether chain and a longer poly-ethylenoxy chain could undergo a photoinduced single electron transfer cyclization reaction in methanol solvent to provide cylic compounds that were constituted with the shorter thioether chain in high regioselectivity and high yield. The structures of all new compounds were confirmed by NMR and El-MS data.
作者 金英学 谭广慧 王天赤 魏树权 王进军
机构地区 哈尔滨师范大学化学化工学院 烟台大学化学生物理工学院
出处 《有机化学》 SCIE CAS CSCD 北大核心 2010年第4期595-600,共6页 Chinese Journal of Organic Chemistry
基金 国家自然科学基金(No.20972036) 黑龙江省教育厅海外学人科研基金(No.1152hq23) 国家人事部留学人员科技活动项目择优资助 教育部留学回国人员科研启动基金(No.[2008]890) 山东省自然科学基金(No.Y2008B49)资助项目
关键词 二供电子链 邻苯二甲酰亚胺 单电子转移 环化反应 electrondonating bis-chain phthalimide single electron transfer cyclization reaction
分类号 O621.25 [理学—有机化学]
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参考文献13

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二级参考文献33

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共引文献4

同被引文献21

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有机化学
2010年 第4期

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