摘要
本文报道了希夫碱配体，Ｎ（二茂铁基１甲基甲叉）肼基硫代甲酸甲酯（简称为ＨＬ）的双二茂铁三核镍配合物的合成和表征。单晶Ｘ射线结构分析表明镍原子的配位构型为奇异的顺式平面正方形，两个二茂铁基团在镍原子的同一边。电化学测定表明正方形的镍配合物能有效地传递两个二铁基团间的电子转移。
The Synthesis and characterization of a novel biferrocene trinuclear nickel (Ⅱ) complex with Schiff base ligand, S methyl N(ferrocenyl 1 methyl methylidene) dithiocarbazate (hereafter abbreviate as HL), are described, X ray diffraction studies established that the coordinated geometry of Ni(Ⅱ) is close to square planar and in novel cis configuration with two ferrocene moieties in the same side Electrochemical measurements suggest that the square planar configuration of the Ni(Ⅱ) can effectively transmit the redox effects of the ferrocene moieties
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
1998年第4期437-444,共8页
Chinese Journal of Inorganic Chemistry
基金
国家自然科学基金
关键词
双二茂铁
电化学
晶体
三核
电子转移
镍配合物
biferrocene electrochemistry crytstal structure\ \ electron transfer
