摘要
研究了以ＤＬ高胱氨酸（ＤＬＨＣ）为原料，铅合金作阴、阳极材料，在盐酸水溶液中电解合成ＤＬ高半胱氨酸硫内酯盐酸盐（ＤＬＨＣＴ）的新工艺。结果表明，当体系温度控制３０～４０℃、槽压４０～５０Ｖ、电流密度４５０～６００Ａ·ｍ－２、反应物浓度２０ｍｏｌ·Ｌ－１以及通入理论电量１２０％时，产品收率可达９２０％左右，含量≥９９０％。
DLHomocysteine thiolactone hydrochloride (DLHCT) is electrosynthesized at cathode Pb alloy from reduction of DLhomocystine (DLHC) in the hydrochloric acid solution .The results show the product yield is about 92.0% if the suitable conditions are controlled as following:temperature is 30～40℃,cell voltage is 4.0～5.0V,current density is 450～600A/m^2,concentration of reactant is 2.0mol·L^-1,quantity of electricity is 1.2fold of theoretical amount,content of the product is above 98.5%.
出处
《精细化工》
EI
CAS
CSCD
北大核心
1998年第2期52-55,共4页
Fine Chemicals
关键词
胱氨酸
半胱氨酸硫内酯
盐酸盐
电解
DLhomocystine,DLhomocysteine thiolactone hydrochloride,electrosynthesis
