摘要
以３－羟基－２－萘酸为原料，通过溴化、还原、酯化、亚硝化等一系列反应制得中间体４－亚硝基－７－溴－２－萘酸甲酯（Ⅳ）．化合物（Ⅳ）与费歇尔碱缩合即得题示化合物——Ｎ－十八烷基－３，３－二甲基－５′－甲氧羰基－８′－溴吲哚啉螺萘并口恶嗪（Ⅴ）．通过元素分析、红外光谱、核磁共振等手段对合成的中间体及目标分子的结构进行了表征．化合物（Ⅴ）具有光致变色性能．
An intermediater 4 nitroso 7 bromo 3 hydroxyl naphthalene methylcarboxylate (Ⅳ) was obtained by bromination,reduction,esterification and nitrosylation from 3 hydroxyl 2 naphthalenecarboxylic acid.Then the title compound N alkyl 3, 3 dimethyl 5′ methoxycarbonyl 8 bromo indolinospironaphthoxazine (Ⅴ) was synthesised by the cyclo condendensation of (Ⅳ) with Fischer base.The structures of these compounds obtained were identified by elemental analysis,IR and 1HNMR.
出处
《中南工业大学学报》
CSCD
北大核心
1998年第6期596-598,共3页
Journal of Central South University of Technology(Natural Science)
基金
国家自然科学基金
