摘要
电化学环氧化反应的研究已引起了人们的重视,但反应机理的研究报道还较少。我们曾研究了环己烯的电化学环氧化反应机理,本文用卷积扫描电位伏安法、恒电位阶跃法进一步研究了该环氧化反应的动力学特性。
The electrochemical epoxidation of cyclohexene on smooth platinum was investigated by means of convolution potential sweep voltammetry and potential step in H2O-NaBr-MeCN- system. It is further proved that the electrochemical oxidation of Br- is irreversible in the system, and the electrochemical epoxidation of cyclohexene shows a characteristic of EC catatytic mechanism. Based on the analysis of data, some kinetic parameters were determined.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
1989年第12期1260-1262,共3页
Chemical Journal of Chinese Universities
关键词
环己烯
环氧环己烷
电化学环氧化
Electrochemical epoxidation, Potential step, Convolution potential sweep voltammetry, Cyclohexene, Epoxycyclohexane
