摘要
具有抗癌作用的硫代脯氨酸可作为双齿配体与具有类金属属性的二芳基硼形成螫合物.本文报道9种这类新配合物,研究了IR、MS、NMR波谱.除配合物2和9外,这类配合物大都产生由于明显的芳基偶联作用而出现的碎片峰.
Thioproline which can induce the cancer cells to lose the characteristics of tumoral transformation unites with diaryl boron group, forming pseudometal-chelated compound. The structures of nine compounds were confirmed by elemental analysis,and IR,MS and NMR spectrometries.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
1989年第9期881-885,共5页
Chemical Journal of Chinese Universities
关键词
硼配合物
二芳基硼
硫代脯氨酸
Organoboron compound, Heterocyclic compound,Chelate compound,Thiazolidine-4-car-boxylic acid, Thioproline