摘要
测量反应体系压力变化的装置已有报道,但本文装置具有操作方便、记数准确等优点。 1 实 验 1.1 实验原理及试剂 详见文献。 1.2 装置及仪器 本文的无汞动力学测量装置用于乙炔氢氯化均相催化反应力学研究,其组装图如图1所示。
A kind of non-mercury kinetic equipment to measure-the changes in the pressure of a reaction system has been designed. Using this equipment, we have studied the kinetics of the reaction of acetylene hydrochlorination in hydrochloric acid with catalyst HgCl2. The reaction apparent activation energy is 58.2kJ/mol. The results showed that the equipment is very convenient to operating and designed to give the accurate recordings.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
1989年第3期320-321,共2页
Chemical Journal of Chinese Universities
关键词
无汞测压
动力学装置
氢氯化
乙炔
Non-mercury kinetic equipment, Hydrochlorination, Acetylene
