摘要
In order to obtain anatase TiO2/expanded graphite with high expansion volume, titania gel was introduced to expandable graphite surface by sol-gel process, and then the composite was expanded and calcined at high tempera- ture. The samples were analysed by using scanning electron microscope （SEM）, X-ray diffraction（XRD）, energy disperse spectroscopy （EDS）, and differential scanning calorimetry （DSC）. The optimal conditions for preparation are as follows： the molar ratio of tetrabutyl orthotitanate to triethanolamine is 1 ： 0.4, and the calcination and expansion temperature is in the range of 650--750 ~C. Under such conditions, the expansion volume of composites could reach 98 mE/g, and the mass loss ratio is less than 5%. The analysis shows that lower temperature and smaller particle size of graphite are helpful to the formation of anatase-type of TiO2, but larger particle size will lead to lower mass loss ratio, and higher temperature and larger particle size will lead to higher expansion volume.
In order to obtain anatase TiO2/expanded graphite with high expansion volume, titania gel was introduced to expandable graphite surface by sol-gel process, and then the composite was expanded and calcined at high temperature. The samples were analysed by using scanning electron microscope (SEM), X-ray diffraction(XRD), energy disperse spectroscopy(EDS), and differential scanning calorimetry(DSC). The optimal conditions for preparation are as follows: the molar ratio of tetrabutyl orthotitanate to triethanolamine is 1∶0.4, and the calcination and expansion temperature is in the range of 650-750 °C. Under such conditions, the expansion volume of composites could reach 98 mL/g, and the mass loss ratio is less than 5%. The analysis shows that lower temperature and smaller particle size of graphite are helpful to the formation of anatase-type of TiO2, but larger particle size will lead to lower mass loss ratio, and higher temperature and larger particle size will lead to higher expansion volume.
基金
Supported by Applied Basic Research Project of Sichuan Province (No.2006J13-014)
Innovation Fund of Panzhihua University
