摘要
Amercury(Ⅱ)coordinationpolymerwith1,5,9-triselena[9]ferrocenophane(L),[HgI2L·0.5C4H4O·0.5CH3OH]n, has been synthesized and characterized. The X-ray crystal structure shows that bridging by the ligand L causes compound to form one-dimensional chain. The half-wave potential of 1,1′-ferrocenylene group is more negative than that of the "free" ligand, which reveals no through-space interaction Hg…Fe in the coordination polymers.
A mercury（Ⅱ） coordination polymer with 1,5,9-triselena[9]ferrocenophane （L）, [HgI2L·0.5C4H4O·0.5CH3OH]n, has been synthesized and characterized. The X-ray crystal structure shows that bridging by the ligand L causes compound to form one-dimensional chain. The half-wave potential of 1,1′-ferrocenylene group is more negative than that of the “free” ligand, which reveals no through-space interaction Hg…Fe in the coordination polymers. CCDC： 742585.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2010年第2期339-342,共4页
Chinese Journal of Inorganic Chemistry
基金
江苏省高校自然科学基金(No.08kjb150008)
教育部留学回国人员启动基金
关键词
汞髤
1
5
二茂铁环蕃
配位聚合物
Mercury（Ⅱ）
1,5,9-Triselena[9]ferrocenophane
coordination polymer
