期刊文献+

可视嗅觉系统对4种环状有机胺的识别 被引量:3

Recognition of four cyclic amines with smell-seeing system
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摘要 介绍了可视嗅觉敏感阵列的制作方法,并用自行设计的可视嗅觉检测系统对苯胺,N,N-二甲基苯胺,环己胺和吡啶这4种分别具有芳香环,脂肪环和杂环结构的环状有机胺进行了识别。实验结果表明,可视嗅觉敏感阵列对这4种有机胺的静态图像响应模式和动态时间响应模式具有高度的特异性,并且可以分辨相互间分子结构和电子属性的类似性。 A developing method of smell-seeing sensitive arrays is presented. The developed arrays are then equipped in a self-designed smell-seeing system to recognize four cyclic amines with three kinds of different molecular ring structures. Two of them are aniline and N,N-dimethylaniline with aromatic ring structure; the third one is cyclohexylamine with aliphatic ring structure; and the last one is pyridine with heterocyclic structure. Results show that both static image response patterns and dynamic time response patterns of the sensitive arrays for the four amines are highly specific to each other. Moreover, the system can perceive the similarities of the molecular structural and electronic properties among the four analytes.
出处 《仪器仪表学报》 EI CAS CSCD 北大核心 2010年第1期183-187,共5页 Chinese Journal of Scientific Instrument
基金 西北工业大学基础研究基金资助(w018103) 西北工业大学博士论文创新基金(cx200910)资助项目
关键词 可视嗅觉 有机胺 电子鼻 金属卟啉 smell-seeing amines electronic nose metalloporphyrins
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参考文献10

  • 1JANZEN M C, PONDER J B, BALLEY D P, et al. Colorimetric sensor arrays for volatile organic compounds[J]. Analytical Chemistry, 2006, (78) : 3591-3600.
  • 2WANG J Y, Z A, LUTHEY-SCHULTEN, SUSLICK K S. Is the olfactory receptor a metalloprotein[J] PNAS, 2003, 100(6): 3035-3039.
  • 3MOMBAERTS E Odorant receptor genes in humans[J]. Science, 1999, (286): 707-711.
  • 4SUSLICK K S, RAKLOW N A. A Colorimelric Nose: "Smell-Seeing"[J].Artificial Chemical Sensing: Olfaction and the Electronic Nose. Stetter, J R., Pensrose, W R. Electrochem. Soc.: Pennington, NJ, 2001: 8-14.
  • 5NATALE C D, PAOLESSE R, D'Amico A. Metalloporphyrins based artificial olfactory receptors[J]. Sensors and Actuators B, 2007,( 121): 238-246.
  • 6ZHENG W Q, SHAN N, YY L X, et al. UV-visible, fluo-rescence and EPR properties of porphyrins and metalloporphyrins[J]. Dyes and Pigments, 2008, (77): 153-157.
  • 7V. CAMPO D O, CARBALLO R, HURST J A, et al. UV-vis spectroscopic study of Co01)/Co(III)oxidation in poly[M-protoporphyrins] films and their interaction with axial ligands[J]. Spectrochimica Acta Part A, 2005, (61): 2089-2093.
  • 8GOUTERMAN M. Spectra of porphyrins[J]. Journal of Molecular Spectroscopy, 1961, (6): 138-163.
  • 9ABDELHAMID R F, OBARA Y, UCHIDA Y, et al. Pi-pi interaction between aromatic ring and copper-coordinated His81 irnidazole regulates the blue copper active-site structure[J]. Journal of biological inorganic chemistry, 2007, 12 (2): 165-173.
  • 10SEN A, ALBARELLA J D, CARAY J R. Low-cost colorimetric sensor for the quantitative detection of gaseous hydrogen sulfide[J]. Sensors and Actuators B: Chemical, 2008, 13(1): 234-237.

同被引文献40

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  • 2许钟,杨宪时,肖琳琳.低温贮藏罗非鱼微生物学质量变化特性和保藏期[J].中国海洋大学学报(自然科学版),2005,35(4):621-625. 被引量:28
  • 3邹小波,赵杰文.基于小波去噪和支持向量机的苹果品种识别法[J].仪器仪表学报,2007,28(3):534-538. 被引量:18
  • 4曹小安 张新荣.检测易爆气体的催化发光阵列传感器研究.广西师范大学学报,2003,21(4):293-294.
  • 5VENKATASAMI G, JOHN R. A rapid, acetonitrile-free, HPLC method for determination of melamine in infant formula [ J ]. Analytica Chimica Acta, 2010 (665) : 227 -230.
  • 6YAN CH, DONG Y Y, WU J H, et al. Screening melamine adulterant in milk powder with laser Raman spectrometry [ J ]. Journal of Food Composition and Analysis, 2010( 23 ) : 199-202.
  • 7HUODQ, YANGLM, HOU C J, et al. Molecular interactions of monosulfonate tetraphenylporphyrin (TPPS1) and meso-tetra (4-sulfonatophenyl) porphyrin (TPPS) with dimethyl methylphosphonate (DMMP) [ J]. Spectrochimica Acta Part A-Molecular and Biomolecular Spectroscopy, 2009,74 (2) : 336 -343.
  • 8DINATALE C, PAOLESSE R. Metalloporphyrins based artificial olfactory receptors [ J ].Sensors and Actuators B, 2007( 121 ) :238-246.
  • 9PENZA M, ROSSI R, ALVISI M, et al. Metalloporphyrins- functionalized carbon nanotube networked films for room-temperature VOCs sensing applications [ J ]. Procedia Chemistry, 2009 ( 1 ) : 975-978.
  • 10PAOLESSE R, DINATALE C, BURGIO M, et al. Por3hyrin- based array of cross-selective electrodes for analysis of liquid samples[ J]. Sensors and Actuators B, 2003 ( 95 ) :400-405.

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