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Solvo-thermal synthesis and characterization of nest-like zinc oxide 被引量:2

Solvo-thermal synthesis and characterization of nest-like zinc oxide
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摘要 With Zn(NO3)2·6H2O and NaOH as starting materials, a novel nest-like ZnO nanostructure was successfully synthesized by a solvo-thermal method. The products were characterized by X-ray diffraction, photoluminescence and scanning electron microscopy. The growth mechanism of the nest-like ZnO was discussed. The results show that the as-synthesized samples have a wurtzite structure, with a weak UV emission at about 395 nm, a green emission at around 557 nm and a blue-green emission at 453 nm. SEM investigation reveals that the growth route of the nest-like ZnO can be considered involving three stages: nano-sized ZnO sheet can be firstly achieved, then outspreads quickly and increasingly becomes a long fishbone-like strip with many branch sheets, and finally these sheets curl into a nest-like structure. With Zn(NO3)2.6H2O and NaOH as starting materials, a novel nest-like ZnO nanostructure was successfully synthesized by a solvo-thermal method. The products were characterized by X-ray diffraction, photoluminescence and scanning electron microscopy. The growth mechanism of the nest-like ZnO was discussed. The results show that the as-synthesized samples have a wurtzite structure, with a weak UV emission at about 395 nm, a green emission at around 557 nm and a blue-green emission at 453 nm. SEM investigation reveals that the growth route of the nest-like ZnO can be considered involving three stages: nano-sized ZnO sheet can be firstly achieved, then outspreads quickly and increasingly becomes a long fishbone-like strip with many branch sheets, and finally these sheets curl into a nest-like structure.
机构地区 College of Science
出处 《中国有色金属学会会刊:英文版》 CSCD 2010年第1期119-122,共4页 Transactions of Nonferrous Metals Society of China
基金 Projects(09JCYBJC04200, 05yfJMTC 12900) supported by the Natural Science Foundation of Tianjin, China
关键词 氧化锌 热合成 表征 扫描电子显微镜 纳米结构 绿光发射 X射线衍射 ZnO morphology solvo-thermal synthesis growth mechanism nest-like structure
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参考文献21

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