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柔性有机太阳能电池基板COC的表面物理化学性能研究 被引量:4

Physicochemical Performance of COC Substrates for Flexible Organic Solar Cells
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摘要 采用氧等离子体处理对柔性有机太阳能电池(O SC)基板环烯烃共聚物(COC)进行表面改性,基于接触角测量,利用几何平均法计算了COC表面自由能及其极性分量、色散分量以及表面极性度,研究了氧等离子体处理对COC基板表面物理化学性能的影响.结果表明:COC基板表面性能与氧等离子体处理工艺条件密切相关,等离子体改性使得COC表面接触角减小、自由能增大、极性度增加,其表面物理化学性能得到明显优化.这-结果对于O SC柔性电极制备及其器件光伏性能改善具有重要作用. Surface modification of the cyclic olefin copolymer(COC) substrates for flexible organic solar cells(OSC) was carried out with oxygen-plasma treatment.Based on the measurements of the contact angles by the sessile drop technique,the surface free energy and polarity of the COC substrates were calculated using the geometric mean approach.The effect of oxygen-plasma treatment on the surface physicochemical property of COC substrates was investigated.The experimental results show that the oxygen-plasma treatment decreases contact angle,increases surface free energy and enhances surface polarity,and therefore improves effectively surface physicochemical property of COC substrates.The results indicate that the oxygen-plasma treatment is beneficial to the preparation of flexible electrode and the improvement of photovoltaic performance of flexible OSC.
出处 《中南民族大学学报(自然科学版)》 CAS 2009年第4期38-42,共5页 Journal of South-Central University for Nationalities:Natural Science Edition
基金 湖北省自然科学基金资助项目(2009CDB166) 中南民族大学自然科学基金资助项目(YZZ07004)
关键词 有机太阳能电池 基板 物理化学性能 organic solar cells substrate physicochemical performance
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参考文献15

  • 1Brabec C J, Sariciftci N S, Hummelen J C. Plastic solar cells[J]. Adv Funct Mater, 2001, 11(1): 15- 26.
  • 2Tang C W. Two-layer organic photovoltaic cell [J]. Appl Phys Lett, 1986, 48(2): 183-185.
  • 3Breeze A J, Schlesinger Z, Carter S A, et al. Charge transport in TiO2/MEH-PPV polymer photovoltaics [J]. Phys Rev B, 2001, 64(12): 125205-1-9.
  • 4Li G, Shrotriya V, Huang J, et al. High-efficiency solution processable polymer photovoltaie cells by self-organization of polymer blends[J]. Nat Mater, 2005, 4(11): 864-868.
  • 5Yang X N, Loos J, Veenstra S C, et al. Nanoscale morphology of high-performance polymer solar cells [J]. Nano Lett, 2005, 5(4): 579-583.
  • 6Steim R, Choulis S A, Schilinsky P, et al. Interface modification for highly efficient organic photovoltaics [J]. Appl Phys Lett, 2008, 92(9): 093303-1-3.
  • 7顾锦华,钟志有,何翔,孙奉娄.真空退火处理对光敏薄膜及聚合物太阳电池性能的影响[J].中南民族大学学报(自然科学版),2009,28(3):30-33. 被引量:22
  • 8Kim J Y, Lee K, Coates N E, et al. Efficient tandem polymer solar cells fabricated by all-solution processing[J]. Science, 2007, 317(5 835): 222-225.
  • 9Al-Ibrahim M, Roth H K, Zhokhavets U, et al. Flexible large area polymer solar cells based on poly (3-hexylthiophene)/fullerene [J]. Sol Energy Mater Sol Ceils, 2005, 85(1): 13-20.
  • 10Lungenschmied C, Dennler G, Neugebauer H, et al. Flexible, long-lived, large-area, organic solar cells [J]. Sol Energy Mater Sol Cells, 2007, 91(5): 379- 384.

二级参考文献13

  • 1康博南,王立铎,邱勇.不同分子量MEH-PPV光伏特性比较[J].科学通报,2004,49(16):1611-1613. 被引量:3
  • 2Brabec C J, Sariciftci N S, Hummelen J C. Plastic solar cells[J]. Adv Funct Mater, 2001, 11(1): 15- 26.
  • 3Tang C W. Two-layer organic photovoltaic cell[J]. Appl Phys Lett, 1986, 48(2): 183-185.
  • 4Breeze A J, Schlesinger Z, Carter S A, et al. Charge transport in TiO2/MEH-PPV polymer photovoltaics [J]. Phys RevB, 2001, 64(12): 125205-1-9.
  • 5Li G, Shrotriya V, Huang J, et al. High-efficiency solution processable polymer photovoltaic cells by self-organization of polymer blends[J]. Nat Mater, 2005, 4(11): 864-868.
  • 6Yang X N, Loos J, Veenstra S C, et al. Nanoscale morphology of high-performance polymer solar cells [J]. NanoLett, 2005, 5(4): 579-583.
  • 7Kim J Y, Lee K, Coates N E, et al. Efficient tandem polymer solar cells fabricated by all-solution processing[J]. Science, 2007, 317(5835): 222-225.
  • 8Steim R, Choulis S A, Schilinsky P, et al. Interface modifycation for highly efficient organic photovoltaics [J]. Appl Phys Lett, 2008, 92(9): 093303-1-3.
  • 9Hauch J A, Schilinsky P, Choulis S A, et al. Flexible organic P3HT: PCBM bulk-heterojunction modules with more than 1 year outdoor lifetime[J]. Sol Energy Mater Sol Cells, 2008, 92(7): 727-731.
  • 10Moss T S, Burrell G J, Ellis B. Semiconductor Optoelectronics[M]. London:Butterworths, 1973.

共引文献21

同被引文献108

  • 1顾锦华,钟志有,何翔,孙奉娄,陈首部.有机太阳能电池内部串并联电阻对器件光伏性能的影响[J].中南民族大学学报(自然科学版),2009,28(1):57-61. 被引量:13
  • 2钟志有,蒋亚东,王涛,黎威志,季兴桥.有机层界面电荷聚集及其对OLED性能的影响[J].半导体光电,2005,26(6):527-530. 被引量:3
  • 3黎立桂,鲁广昊,杨小牛,周恩乐.聚合物太阳能电池研究进展[J].科学通报,2006,51(21):2457-2468. 被引量:31
  • 4Kim J Y, Lee K, Coates N E, et al. Tandem polymer solar cells fabricated by all-solution processing [J]. Science, 2007, 317(5835): 222-225.
  • 5Breeze A J,Schlesinger Z, Carter S A, et al. Charge transport in TiO2/MEH-PPV polymer photovoltaics [J]. Phys. Rev. B, 2001, 64(12): 125205-1-9.
  • 6Zhong Z Y. Surfacemodification and characterization of indium-tin oxide for organic light-emitting devices [J]. Colloid Interface Sci. , 2006, 302(2) : 613-619.
  • 7You Z Z. An investigation into the effects of oxygen plasma discharge on tin-doped indium oxide thin films [J]. J. Electron Spectrosc. Relat. Phenom., 2007,160(1/3): 29-34.
  • 8Necliudov P V, Shur M S. Modeling of organic thin film transistors of different designs [J]. J. Appl. Phys., 2000, 88(11): 6594-6597.
  • 9Abel,s F. Optical Properties of Solids [ M ]. Amsterdam: North-Holland Publishing Company, 1972.
  • 10You Z Z, Hua G J. Refractive index, optical handgap and oscillator parameters of organic films deposited by vacuum evaporation technique[J]. Vacuum, 2009, 83(6) : 984-988.

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