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[Cu(en)_2]_2[Cu(en)_2(H_2O)][PW_(11.5)Cu_(0.5)O_(40)]·OH·3H_2O的水热合成及结构表征

Hydrothermal Synthesis and Structure of [Cu(en)_2]_2[Cu(en)_2(H_2O)][PW_(11.5)Cu_(0.5)O_(40)]·OH·3H_2O
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摘要 利用水热合成法制备了基于Keggin结构阴离子的1D链状化合物[Cu(en)2]2[Cu(en)2(H2O)][PW11.5Cu0.5O40].OH.3H2O,并经红外、紫外和X射线单晶衍射等手段进行了表征.标题化合物属于单斜晶系,P21/c空间群,晶胞参数:a=1.266 25(10),b=2.145 45(19),c=2.455 95(18)nm,β=114.919(3),V=6.050 9(8)nm3,Z=4,R1=0.068 1,wR2=0.146 8. A 1D chain compound based on Keggin anion [Cu（en）2]2[Cu（en）2（H2O）][PW11.5Cu0.5O40]·OH·3H2O was hydrothermally synthesized and characterized by IR,UV spectrometry and X-ray single-crystal diffraction.The title compound crystallizes in monoclinic system,P21/c space group,cell parameter： a=1.266 25（10）,b=2.145 45（19）,c=2.455 95（18） nm,β=114.919（3）,V=6.050 9（8） nm3,Z=4,R1=0.068 1,wR2=0.146 8.
作者 祁素芳 杨林平 宋一平 马鹏涛
机构地区 河南大学化学化工学院分子与晶体工程研究所
出处 《化学研究》 CAS 2009年第4期59-61,64,共4页 Chemical Research
基金 国家自然科学基金(20771034) 河南大学校内基金自然科学重点项目(062D2R0101)
关键词 聚金属氧酸盐 水热合成 配合物 KEGGIN结构 polyoxometalate hydrothermal synthesis coordination compound Keggin structure
分类号 O643.38 [理学—物理化学]
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参考文献15

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化学研究
2009年 第4期

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