摘要
The effect of Fe-doping on the magnetic properties of the ABO3-type perovskite cobaltites La0.7Ba0.3CoO3(0≤ y≤0.80) is reported. With no apparent structural change in any doped sample, the Curie temperature (Tc) and the magnetization (M) are greatly suppressed for y ≤0.30 samples, while a distinct increase in Tc for the y=0.40 sample is observed. With the further increase of Fe concentration, Tc increases monotonically. Griffiths-like phases in 0.40≤y ≤0.60 samples are confirmed. The formation of the Griffiths-like phase is ascribed to B-site disordering induced isolation of ferromagnetic (FM) clusters above Tc.
The effect of Fe-doping on the magnetic properties of the ABO3-type perovskite cobaltites La0.7Ba0.3CoO3(0≤ y≤0.80) is reported. With no apparent structural change in any doped sample, the Curie temperature (Tc) and the magnetization (M) are greatly suppressed for y ≤0.30 samples, while a distinct increase in Tc for the y=0.40 sample is observed. With the further increase of Fe concentration, Tc increases monotonically. Griffiths-like phases in 0.40≤y ≤0.60 samples are confirmed. The formation of the Griffiths-like phase is ascribed to B-site disordering induced isolation of ferromagnetic (FM) clusters above Tc.
基金
Project supported by the National Basic Research Program of China (Grant No 2009CB929201)
the National Natural Science Foundation of China (Grant No 10774179)