摘要
含有穴醚Ｎ８Ｏ６配体（Ｌ）的异金属和同金属大环化合物［Ａｇ２ＮａＬ］（ＣｌＯ４）３（１），［Ｃｕ２Ｌ］（ＢＦ４）（ＣｌＯ４）ＤＭＦ０．５ＥｔＯＨ（２），在溶液中，室温下，作了１Ｈ，１３Ｃ和１Ｈ１３ＣＨＭＱＣＮＭＲ谱的测定，归属了所有的１Ｈ，１３Ｃ的谱线．对其在溶液中的配位行为通过１ＨＮＭＲ试验作了简单的讨论．
H, 13 C and HMQC NMR spectra of hetero-metal Ag-Na and homo-metal Cu cryptates with cryptand N 8O 6, Ag 2NaL (ClO 4) 3 (1) and Cu 2L (BF 4)(ClO 4)*DMF* 0.5EtOH (2) have been determined at room temperature in solution. All resonances of the proton and carbon of the complexes were assigned. The solution coordination behavior of the complexes were studied by 1H NMR spectra.
出处
《波谱学杂志》
CAS
CSCD
北大核心
1998年第5期457-460,共4页
Chinese Journal of Magnetic Resonance
