摘要
在常压氧、１１０℃反应条件下，考察了不同金属酞菁在苯乙烯液相氧化中的催化作用。单核金属酞菁中，铁酞菁和锰酞菁几乎无催化活性，铜酞菁的诱导期为２．５ｈ；双核金属酞菁的催化氧化活性要比相应的单核金属酞菁的活性高。ＣｏＰｃ、双核ＭｎＰｃ、双核ＣｏＭｎＰｃ以及双核ＦｅＭｎＰｃ对产物环氧苯乙烷具有较高的选择性，产物环氧苯乙烷与苯甲醛的摩尔比分别为１．７，１．７，１．７，２．１。
The catalytic behavior of some metal phthalocyanine for the catalytic oxidation of styrene under normal pressure of oxygen at 110℃ was investigated. Among the single core metal phthalocyanines, iron and manganese phthalocyanines showed no activity, and copper phthalocyanine had a long inducting period. Meanwhile, the double core metal phthalocyanines exhibited higher catalytic activity than that of the single core phthalocyanines. The experimental results showed that single core cobalt, double core cobalt with manganese, and double core iron with manganese phthalocyanine all had high selectivity to styrene oxide.
出处
《石油化工高等学校学报》
EI
CAS
1998年第4期21-24,共4页
Journal of Petrochemical Universities
基金
辽宁省自然科学基金委员会资助
关键词
催化氧化
苯乙烯
金属酞菁
Catalytic oxidation
Phenylethylene
Metal phthalocyanine
