摘要
对N－羟甲基丙烯酰胺（NAM）的合成工艺做了进一步的研究。结果表明：在丙烯酰胺：甲醛＝1∶1．05（mol比），碱性催化剂存在下，70℃反应3h。转化率可达99％。产品质量稳定，反应液可不经分离直接用作交联剂，降低了生产成本。并提出用固含量法测定溶液中的NAM含量，简易可靠。
N - Methylolacrylamide (NAM) was prepared from HCHO and acrylamide (AM) in the presece of basic catalyst. The optimal reaction conditions were AM: HCHO= 1: 1. 05(moL), pH= 9, temperature 70℃ and reaction time 3~3. 5 h, giving 99% conversion. The reaction mixture, NAM aqueous solution approximately, may be directly applied in the preparation of crosslinking polymers as a crosslinking agent.
出处
《精细石油化工》
CAS
CSCD
北大核心
1998年第6期8-10,共3页
Speciality Petrochemicals
关键词
合成
丙烯酰胺
甲醛
NAM
N-methylolacrylamide
synthesis
acrylamide
formaldehyde
