摘要
以1，6-己二醇、丙烯酸为原料，对甲苯磺酸为催化剂，环己烷为带水剂，对苯二酚和乙酸铜为复合阻聚剂，采用酯化反应合成了1，6-己二醇二丙烯酸酯。结果表明，在丙烯酸／1，6-己二醇（摩尔比）为2．2，催化剂质量分数（占原料总质量）为2．5％，阻聚剂质量分数（占丙烯酸用量）为0．6％，反应时间为4h，反应温度为80～110℃的条件下，产物收率可达90．66％。
1,6 - hexanediol diacrylate （ HDDA ） was prepared by esterification with 1,6 - hexanediol and acrylic acid as raw materials,p -toluene sulfonic acid as catalyst, cyclohexane as water - carrying agent, hydroquinone and copper acetate as inhibitots. The results showed that the product yield was 90.66% ,under the conditions of acrylic acid/1,6 -hexanediol （mole ratio）2. 2, the mass fraction of catalyst （based on total mass of materials） 2.5% , the mass fraction of inhibitor （based on mass of acrylic acid） 0.6% ,reaction time 4 h,reaction temperature 80 - 110 ℃.
出处
《石化技术与应用》
CAS
2009年第6期508-510,共3页
Petrochemical Technology & Application
