摘要
首先导出聚集硬球分子模型状态方程，然后应用该方程计算了５种金属熔体饱和气的密度，取得了非常满意的结果。另外，还应用克拉贝龙方程、蒸汽压方程和状态方程计算了金属熔体的汽化潜热，所得结果与实验数据符合良好。
Based on the theory of molecular aggregation and the model for hard spherical molecule, an equation of state for molecular aggregation is derived by the statistical thermodynamic method. Then, the densities of saturated vapor of 5 melting metallic substances are calculated by using the equation of state, giving quite satisfactory results. In addition, the latent heat of vaporization of the same substances are determined by using the Clapeyron equation and the above equation of state. The results obtained are in good agreement with the experimental data.
出处
《天然气化工—C1化学与化工》
CAS
CSCD
北大核心
1998年第3期56-59,共4页
Natural Gas Chemical Industry
关键词
分子聚集理论
金属熔体
热力学性质
气化
theory of molecular aggregation, melting metallic substance, thermodynamic property
