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氧化·热化学脱硫研究

Study on removal of SO_2 by oxidized·thermal chemical method.
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摘要 热化学脱硫法因铵盐回收率低、产物不稳定,无法解决实用化问题。氧化热化学法应用超强脉冲电场产生高浓度、高能量的活性粒子,使SO2在氧化过程中生成H2SO4,与NH3进行热化学反应,生成稳定的固体微粒(NH4)2SO4,用电收尘器加以回收。脱除率、回收率可达90%左右,脱除1m3烟气中SO2耗能为4Wh,实现了干法高效脱硫。一次投资大幅度减少,回收铵盐基本上抵消了药品费和电费。 Removal of SO2 by thermal chemical method can not be applied due to low collection efficiency of ammonium salts and unstable products. Oxidized ·thermal chemical method applies ultrahigh pulse electric field to produce activated particles of high concentration、high energy , so that SO2 is oxidized to produce H2SO4 and further form stable solid particles (NH4)2SO4 after thermal chemical reaction with NH3,which is collected in electrostatic precipitator (EP).The rate of SO2 removal and collection is up to 90%,and energy consumption in 1m3 flue gas is 4Wh.Therefore,the SO2 removal of high effective dry method is realized.With this method,the once investment is diminished greatly,and the expenses for additive NH3 and electricity are offsetted by the profits of the collection ammonium salts.
出处 《中国环境科学》 EI CAS CSSCI CSCD 北大核心 1998年第4期324-327,共4页 China Environmental Science
关键词 热化学 氧化 活性粒子 脱硫 烟气脱硫 废气处理 thermal chemistry oxidization activated particles collection efficiency
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