摘要
通过对β-环糊精单体的功能化改性合成出BBx′型环糊精大单体,再通过双单体法在紫外光引发的条件下,用BBx′型单体与A2型单体反应,合成出超支化聚(β-环糊精)。对BBx′型环糊精大单体及聚合物的结构进行了表征,结果表明所合成的单体及聚合物与设计的结构相一致。
BBx' type β-cyclodextrin monomer is first synthesized via the modification of β-cyclodextrin monomer, and then hyperbranched poly(β-cyclodextrin) is successfully prepared via ultaviolet initiated double-monomer method from BBx' type and A2 type monomers. The molecular structures of BBx' type monomer and hyperbranched polymer are characterized, and the results indicate that the resultant polymer is in accordance with what is designed.
出处
《现代化工》
CAS
CSCD
北大核心
2009年第8期52-55,共4页
Modern Chemical Industry
基金
国家自然科学基金(20674060)资助项目
关键词
BBx’型环糊精大单体
紫外光引发聚合
双单体法
BBx' type cyclodextrin monomer
ultraviolet initiated polymerization
double-monomer method