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镁铝硅钛铈系微晶玻璃的显微结构及介电性能

Microstructure and dielectric properties of MgO-Al_2O_3-SiO_2-TiO_2-CeO_2 system glass-ceramics
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摘要 选取工业纯原料,采用熔融法制备了镁铝硅钛铈系微晶玻璃,研究其在不同晶化温度下的显微结构及微波介电性能。结果表明:随着晶化温度的提高,微晶玻璃的岛先增大后减小,在1000℃时达到最大值;同时微晶玻璃中晶粒逐渐长大,残余玻璃相减少,tanδ降低;当晶化温度超过1200℃时,晶粒粗化,tanδ略有升高。所制微晶玻璃在微波频率(8GHz)下,其εT在8.55~14.61可调,tanδ小于8×10^-4,是一种性能优良的微波介质材料。 MgO-Al2O3-SiO2-TiO2-CeO2 system glass-ceramics were prepared with industrial-grade raw materials using melting method, and the microstmctures and microwave dielectric properties of the glass-ceramics obtained at different crystallization temperatures were investigated. The results show that with the increasing of the crystallization temperatures, the relative permittivity (εr) of the glass-ceramics increases firstly, which gets its maximum value at 1 000 ℃, then decreases; the growth of the crystals in the glass-ceramics leads to the reduction of residual glass phase and dielectric loss (tang); however, at 1 200℃ above, tang increases slightly due to the coarse of the crystals. The obtained glass-ceramics with εrof 8.55-14.61 and tang less than 8×10-4 at microwave frequency of 8 GHz can be used as promising microwave dielectric materials.
出处 《电子元件与材料》 CAS CSCD 北大核心 2009年第8期17-19,共3页 Electronic Components And Materials
基金 江苏省中青年学科带头人"青蓝工程"资助项目
关键词 无机非金属材料 镁铝硅钛铈系 微晶玻璃 晶化温度 微波介质材料 non-metallic inorganic material MgO-Al2O3-SiO2-TiO2-CeO2 system glass-ceramic crystallizationtemperature microwave dielectric material
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