摘要
采用4种表面改性剂烷基多磷酸酯、硬脂酸钠、柠檬酸单甘酯、十二烷基磷酸酯对超细水镁石粉进行表面改性,以吸水率、接触角为表征手段考察了改性剂种类和用量对超细水镁石粉表面改性的影响。通过2,2,4-三甲基戊烷洗涤后改性水镁石粉接触角的变化,表明改性后的超细水镁石粉由亲水性转变为疏水性,吸附方式既有化学吸附又有物理吸附。将硬脂酸钠改性后的水镁石粉填充到聚烯烃中,结果表明,硬脂酸钠的较佳用量为2%,硬脂酸钠改性水镁石粉的加入使材料的氧指数从29.3%提高到32.9%,断裂伸长率提高了30%。
Super-fine brucite powder was surface modified using several surfactants as modifiers, with the effect of modification characterized through water adsorption and contact angle measure- ments. After being washed with 2, 2, 4-trimethylpentyl, the surface of brucite powder changed from hydrophilic to hydrophobic. Surface modified super-fine brucite powder was used in polyolefin flame retardant formulations. It was found sodium stearate was the best modifier in this study with an optimal dosage about 2 %, resulting in a limited oxygen index of 32. 9% and an elongation at break about 30 % higher than devoid sample.
出处
《中国塑料》
CAS
CSCD
北大核心
2009年第7期61-64,共4页
China Plastics
关键词
水镁石粉
表面改性
聚烯烃
阻燃
brucite
surface modification
polyolefin
flame retardancy
