摘要
合成了二个含2-二苯基膦基氨基吡啶的Pd（Ⅱ）配合物，并进行了元素、红外分析，评价了它们在乙醇羰基化反应中的催化活性．单晶结构测试结果表明，Pd（PAP）Cl2的中心离子和配位原子几乎处于同一平面．
篢wo Pd(Ⅱ) complexes containing 2-(diphenylphosphinoamino) pyridine(PAP) were synthesized. Elementary analysis and IR spectrum were used to characterized them. The catalytic activity of them for carboxylation of ethanol was also tested. The X-ray crystallography of Pd (PAP) Cl2 shows that its center ion Pd (Ⅱ) and other donor atoms are almost in the same plane.
出处
《南开大学学报（自然科学版）》
CAS
CSCD
北大核心
1998年第2期93-95,共3页
Acta Scientiarum Naturalium Universitatis Nankaiensis
基金
国家自然科学基金
关键词
吡啶
乙醇羰化
PAP
钯配合物
催化活性
2-(diphenylphosphinoamonio)pyridine
Pd
carboxylation of EtOH
