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苯胺盐酸盐与瓜环主客体包结物的晶体结构 被引量：1

Crystal Structures of Host-vip Inclusion between Aniline HCl Salt and Cucurbiturils
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摘要 用X射线单晶衍射方法研究六元瓜环和八元瓜环与苯胺盐酸盐的相互作用及其结构特征。从主客体包结配合物的晶体结构,可以看出苯胺的苯环进入了六元瓜环空腔,形成1∶1包结配合物,两分子苯胺以相反的方向平行地进入八元瓜环空腔,形成了2∶1包结配合物;表明苯胺与两种瓜环有不同的作用模式。 Structures of host-vip inclusion complexes of aniline hydrochloride with cucurbit [ n, n = 6 or 8 ] uril have been characterized with Single crystal X-ray diffraction. The crystal structures of these host-vip complexes reveal clearly that the aniline hydrochloride entered into cavity of cucurbit[ 6 ] uril and the inclusion complex was formed in a ratio of 1 ： 1, two aniline hydrochlorides in contrary parallel, however, have been enclosed in cucurbit[ 8 ] uril.
作者 赵芳芳 丛航 陶朱 薛赛凤 祝黔江
机构地区 贵州大学应用化学研究所
出处 《贵州大学学报（自然科学版）》 2009年第2期136-138,共3页 Journal of Guizhou University:Natural Sciences
关键词 瓜环 苯胺 X-射线单晶衍射 主客体包结物 超分子 cucurbit uril aniline single crystal X-ray diffraction
分类号 O613.3 [理学—无机化学]
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参考文献16

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二级参考文献119

共引文献107

同被引文献22

  • 1郑利梅,朱建男,张云黔,陶朱,薛赛凤,祝黔江.1,4二环己基取代六元瓜环与Sr(II)自组装实体的合成与晶体结构[J].贵州大学学报（自然科学版）,2005,22(2):152-157. 被引量：7
  • 2郑利梅,祝黔江,朱建男,张云黔,陶朱,薛赛凤,魏赞斌,龙腊生.1,4二环己基取代六元瓜环与Na(Ⅰ)自组装实体的合成与晶体结构[J].无机化学学报,2005,21(10):1583-1588. 被引量：11
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贵州大学学报（自然科学版）
2009年 第2期

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