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2-巯基苯并噻唑Zn(Ⅱ)和Cd(Ⅱ)配合物的一步法合成及其谱学性质 被引量：1

A New Synthesis Method and Spectroscopy Characterization of the Complex of Zn(Ⅱ) and Cd(Ⅱ) with 2-Hmbt
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摘要 Zn(NO3)2.6H2O和Cd(NO3)2.4H2O与2-巯基苯并噻唑(2-Hmbt)及L配体(L=2,2′-bipy,1,10-phen)反应,用绿色化学的合成方法得到了三种三元配合物Zn(C7H4NS2)2(2,2′-bipy)(1)、Zn(C7H4NH2)2(1,10-phen)(2)和Cd(C7H4NS2)2(2,2′-bipy)(3),三种配合物均采用红外光谱、元素分析对配合物的组成、结构和光谱性质进行了测试和表征,(1)用1H核磁共振谱进行了性质测试与表征. The reaction of Zn（NO3）2·6H2O、CD（NO3）2· 4H2O with 2-mercaptobenzothiazole （2-Hmbt） and L ligand（ L = 2,2＇- bipy, 1,10-phen）leads to the formation of the complexes Zn（ C7 H, NS2 ）2 （2,2＇-bipy） （1） .Zn（ C7H4NS2 ）2 （1,10-phen） （2） and Cd （C7H4NS2）z （2, 2＇-bipy）（3）. The complexes were characterized by elemental analysis, infrared spectroscopy, complex（ （1） ） characterized by 1 H NMR.
作者 周丽丽 杨晓东 孙静静 金琼花
机构地区 首都师范大学化学系
出处 《首都师范大学学报（自然科学版）》 2009年第3期17-19,24,共4页 Journal of Capital Normal University：Natural Science Edition
基金 国家自然科学基金(20206001) 国家教育部留学回国人员科研启动基金 北京市教委项目(KM200610028006) 北京市留学人员科技活动择优资助项目
关键词 ZN CD 2-Hmbt 2 2'-Bipy 1 10-PHEN 配合物 Zn, Cd, 2-Hmbt, 2, 2＇-bipy, 1, 10-phen, complex.
分类号 O614.24 [理学—无机化学]
  • 相关文献

参考文献7

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同被引文献10

  • 1Hursthouse M B, Khan O F, Mazid Z M, Montevallu M, Brien P O. The X-ray crystal structures of the cadmium complexes of pyridine-1 -thiol and mercaptobenzothiazole, [ Cd ( C5 H4 NS ) 2 ], and [ Cd ( C7 H4 N2 S2 ) 2 ]n : Two unusual volatile polymeric complexes[ J]. Polyhedron, 1990, 9:541.
  • 2Kang B S, Chen Z N, Tong Y X, Liu H Q, Gao H R, Wu B M, Thomas C W Mak. Synthesis and structure of Mn ( II) , Cu( II ) and Zn( II ) complexes containing bis--imidazole ligands [J].Polyhedron, 1997,16:1731.
  • 3Jian F F, Xiao H L, Bai Z S, Zhao P S. Synthesis, characterization and nonlinear optical effects of M4 ( μ^4 -O ) core complexes with large two-photon absorption cross-section[J]. Journal of Materials Chemistry, 2006, 16(38) :3746.
  • 4Jin Q H, Gao H W, Dong J C. Crvtal structure of μ^4-oxo-hexakis( μ-2-mercaptobenzothiazolato-N,S' )-tetrazinc( II ), Zn40(C7H5NS2)6[J]. Z Kristallogr NCS, 2007, 222:233.
  • 5Jin Q H, Zhou L L, Xu L J, Zhang C L, Lu X M. Investigation of isomeric polymers [Cd2(mbt)4]. and [Cd (mbt) 2 ]n: the crystal structure of catena-tetra ( 2-mercaptobenzothiazole ) dicadmium, { [ Cd ( μ-η^2-C7 H4 NS2 ) 2 ] [ Cd ( μ-η2-C7H4NS2 ) ( μ3-η^2-CTH4NS2 ) ]} t o [ J]. J Chem Crystgr, 2009 (submitted).
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引证文献1

首都师范大学学报（自然科学版）
2009年 第3期

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