摘要
本文得出了PbS和PbO交互反应的速率方程:(da)/(dt)=kx_(PbS)~3x_(PbO)^(-2);发现了反应过程中有过渡产物碱式硫酸铅(PbSO_4·2PbO);从电子转移角度,探讨了反应机理。
The rate equation of reaction between PbS and PbO is da/dt=kx_(PbS)~3x_(PbO)^(-2).A transition product, PbSO_4·2PbO, is found by X-ray diffraction analysis. The reac-tion mechanism was discussed on the basis of electron transfer.
出处
《金属学报》
SCIE
EI
CAS
CSCD
北大核心
1990年第2期B077-B081,共5页
Acta Metallurgica Sinica
关键词
PBS
PBO
反应
动力学
电子转移
PbO
PbS
kinetics
transition product
electron transfer
