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4-乙烯基吡啶 - 苯乙烯共聚物正离子与十二基烷基硫酸钠相互作用研究 被引量:8

INTERACTION OF SODIUM DODECYL SULFATE WITH CATIONIC POLYELECTROLYTE DERIVED FROM POLY (4 VINYL PYRIDINE STYRENE)
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摘要 4乙烯基吡啶苯乙烯共聚物正离子与十二基烷基硫酸钠相互作用研究郑晓亮曹维孝(北京大学化学与分子工程学院北京100871)关键词4乙烯基吡啶苯乙烯共聚物正离子,十二烷基硫酸钠,疏水相互作用,胶束交联水溶性聚合体尤其是聚电解质与表面活性剂相互... The interaction of sodium dodecyl sulfate(SDS) with cationic polyelectrolyte derived from poly(4 vinyl- pyridine styrene) hes been investigated. It was found that there has been a narrow molar ratio region of SDS/cation at which the viscosity of aqueous solution rises suddenly due to the aggregation of the SDS attached on cationic polymer, then falls sharply as the SDS/cation ratio is beyond the region because of the deaggregation. At a suitable condition a reversible gelation was observed. A suggestion for explaining the specific phenomena was proposed.
出处 《高分子学报》 SCIE CAS CSCD 北大核心 1998年第3期377-380,共4页 Acta Polymerica Sinica
基金 国家自然科学基金
关键词 乙烯基吡啶 苯乙烯 共聚物正离子 相互作用 SDS Poly(4 vinyl- pyridine styrene) cationic plolyelectronlyte, Sodium dodecyl sulfate, Hydrophobic interaction, Micell crosslinking
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参考文献2

  • 1Yu Shuyan,博士学位论文,1997年
  • 2Chu D Y,J Am Chem Soc,1986年,108卷,6270页

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