摘要
基团贡献法研究甲基丙烯酸酯聚合物特性参数冯亚凯孙经武黄家贤李春荣朱端慧王志军胡静（天津大学应用化学系天津３０００７２）（南开大学化学系天津３０００７１）关键词基团贡献，ＭａｒｋＨｏｕｗｉｎｋ方程，甲基丙烯酸２，２，３，３四氟丙酯，甲基丙烯酸酰基...
A series of methacrylate monomers, such as 2,2,3,3-tetrafluoropropyl, acetoxyethyl, propionyloxyethy1,buthyloxyethyl,isobuthyloxyethyl,tertpentanoxythy1 and (2-glycidy1-ether) ethy1 methacrylate, were synthesized. Their homopolymers and copolymers with high molecular weight were obtained by radical polymerization. By measuring with light scattering and viscosity, the MarkHouwink equations of those homopolymers were determined. The group contribution method was used to calculate the values of index of refraction, dn/dc and parameters of MarkHouwink equations of those homopolymers based on cohesive energy, molar volume and molar attraction constant.
出处
《高分子学报》
SCIE
CAS
CSCD
北大核心
1998年第3期350-354,共5页
Acta Polymerica Sinica
关键词
PMAIBE
PMANBE
PMAPE
PMATFP
PMAAE
PMAGEE
性质
Group contribution, MarkHouwink equation, Poly(2,2,3,3-tetrafluoropropy1-methacrylate), Akyloxyethy1-methacrylate,Methacrylate(2-glycidy1-ether ethyl ester, Radical polymerization
